Friday, February 26, 2010

ORGANIC CHEMISTRY: THE HYDROCARBON

Some Definition
Organic chemistry is the science of carbon compounds, which includes the synthesis of these compounds and the study of the reactions of these compounds.
Organic compounds are compounds which contain carbon (with the exception of carbon dioxide, carbon monoxide, carbonates, carbides, and some of cyanides).
Proteins, fats, carbohydrates, vitamins, hormones, cellulose, anesthetics, antibiotics, and enzymes are some examples of organic compounds.
Carbon Bonding
• Carbon atoms can unite with one another by sharing one or more pairs of electron to form chain or cyclic molecules.
• Carbon atoms with four valence electrons can form four covalent bonds.

Hydrocarbons
Hydrocarbons are compounds that contain only carbon and hydrogen. Types of hydrocarbon:
1. Alkanes C
nH2n+2
2. Cycloalkanes C
nH2n+2-2y ; where y is the number of rings.
3. Alkenes C
nH2n
4. Alkynes C
nH2n-2
5. Benzene (aromatic) hydrocarbon

Types of Hybridization for Hydrocarbons

Hydrocarbon Hybridization of the carbon
Alkane Sp3
Alkene Sp2
Alkyne Sp

Alkanes

General formula C
nH2n+2
CH
4 methane
C
2H6 ethane
C
3H8 propane
C
4H10 butane
C
5H12 pentane
C
6H14 hexane
C
7H16 heptane
C
8H18 octane
C
9H20 nonane
C
10H22 dekane

Cycloalkanes
General formula C
nH2n+2-2y


C3H6 cyclopropane

C4H8 cyclobutane

C5H10 cyclopentane

C6H12 cyclohexane


Alkenes


General formula CnH2n

C2H4 ethane (ethylene)

C3H4 propene (propylene)

C4H8 butene

C5H10 pentene


Alkynes


General formula

C2H2 ethyne (acetylene)

C3H4 propyne

C4H6 butyne

C5H10 pentyne


Structural formulas of alkanes




Structural formulas of alkenes and alkynes

Benzene

Resonance

Resonance is a result of the fact that the correct bonding in a molecule is a hybrid (mixture) of all the possible electron structures which can be written.

Resonance energy is the energy required to change a mole of hybrid molecules to a mole of molecules having the single, conventional valence-bond formula.



Benzene, toluene, and other aromatics



Isomerism

Isomers are compounds which have the same molecular formulas, but different structural formulas.

Isomeric compounds can differ both chemically and physically. They can have difference in melting points, boiling points, refractive index, and chemical activity.



to be continued.....